The current study investigated the effect of heat treatment parameters, including solution treatment temperature (STT), time, and quench rate, on the microstructure, defects, and hardness of an Al-16Si-6Cu Shift fork die-cast alloy. The changes in primary silicon particle (PSP) features were examined quantitatively by optical microscopy, coupled with image analysis and SEM equipped with EDS. The biggest PSPs (27 ± 8 µm) and the highest area fraction (23%) were found in the sample solution treated at 470°C and cooled in the furnace. The hardness value increased in heat-treated samples slightly (140–148 BHN). A lower STT (420°C) and a lower ageing time (1 h) are suitable conditions for the heat treatment of an Al-16Si-6Cu die-cast alloy, in which a lower pore area fraction, 1.18, smaller pore, 4.5 μm, along with finer primary silicon, 9.5 ± 3 μm, with higher circularity, 0.38 ± 0.04, was achieved.