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Title Effect of Textural Properties of Y, ZSM-5 and Beta Zeolites on Their Catalytic Activity in Catalytic Cracking of a Middle Distillate Cut Named RCD
Type JournalPaper
Keywords Catalytic cracking heavy hydrocarbons zeolite Y zeolite Beta Zeolite ZSM-5
Abstract In the present study, the performance of three catalysts containing Y, ZSM-5 and Beta zeolite in the catalytic cracking of a kind of middle distillate cut named ”RCD” has been studied. The catalysts were characterized by XRD, FTIR, SEM, N2 adsorption/ desorption and NH3-TPD techniques. Furthermore, deactivated catalysts in terms of type and amount of deposit-ed coke were analysed. Results of catalytic tests showed that Y zeolite per-formed better and it decreased viscosity and density of liquid product by 35% and 3% respectively. This good operating was due to the high surface area (812m2/gr) and higher acidic sites amounts (1.8 mmol NH3/gr) which gives the heavy molecules better accesibility to active acid sites. But more cokes have deposited on Y zeolite which was 50% lower for Beta and ZSM-5 zeolites. Finally, it can be concluded that the ultimate performance of catalysts in catalytic cracking is inluenced by the synergetic efects between the pore structure and acidity.
Researchers Faezeh Mirshafiee (First Researcher), Reza Khoshbin (Third Researcher), Ramin Karimzadeh (Second Researcher)